Abstract
The novel macrocyclic complex [(Bu2Sn)2OL]2•CH3CN (2) has been prepared from the flexible dicarboxylic acid, LH2, (1). Single crystal X-ray diffraction shows that complex 2 has a centrosymmetric structure, with a central rhomboid cyclic Bu4Sn2O2 unit, linked at the oxygen atoms to two exocyclic tin atoms. The dicarboxylate ligands bridge exocylic and endocyclic tin atoms, completing two rings each of 22 atoms, and two of the four carbonyl oxygen atoms coordinate to the exocyclic tin atoms, to raise their coordination state to five and complete two more six-membered, rings.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
