A novel lithium ion-imprinted membrane with robust adsorption capacity and anti-fouling property based on the uniform multilayered interlayer

Abstract

Effective modification strategies contribute to high adsorption capacity, separation efficiency and anti-fouling properties of ion-imprinted membranes. The design of a homogeneous and hydrophilic interlayer between the substrate membrane and ion-imprinted layer is crucial factor for the excellent performance of ion-imprinted membranes. In this study, a novel multilayered interlayer (SiO2@SP-PDA) was developed and uniformly coated on the substrate surface (PVDF membrane). The polydopamine (PDA) prepared via oxidation of sodium periodate (SP-PDA) increases the uniformity of SiO2@SP-PDA modification, which reduces the agglomeration of the ion-imprinted layer, and thereby boosts the adsorption capacity to 231.77 mg·g−1. The prepared ion-imprinted membrane (SiO2@SP-PDA-IIM) exhibits a favorable anti-fouling property due to the incremental hydrophilicity and the presence of SiO2 nano interlayer. Based on the XDLVO theory, it can be deduced that the SiO2 modification increases the membrane surface electron donor tension (γ−), which plays an essential role in enhancing the anti-fouling property of SiO2@SP-PDA-IIM. In this paper, the design of multilayered structure is of great significance to make the ion-imprinted membrane be a potential candidate for Li+ efficient separation in natural water.