Abstract
A novel hydrogen rearrangement reaction was found in benzyl ions that have a (benzyl) group (Z=O or N) at their ortho position. From deuterium labeling experiments, mass analyzed ion kinetic energy spectra with collisional activation, and examination of structure-peak intensity correlation, a mechanism is proposed which involves a direct transfer of hydrogen (hydride) to the structurally remote but spatially close cationic center. The possibility of an alternative, less likely mechanism including an ion/neutral complex and/or a proton-bridged complex has also been discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.