A novel high-resolution laser-melting sampler for discrete analyses of ion concentrations and stable water isotopic compositions in firn and ice cores

Abstract

<p>Ice cores preserve past climatic changes and, in some cases, astronomical signals. Here we present a newly developed automated ice-core sampler that employs laser melting. A hole in an ice core approximately 3 mm in diameter is melted and heated well below the boiling point by laser irradiation, and the meltwater is simultaneously siphoned by a 2 mm diameter movable evacuation nozzle that also holds the laser fiber. The advantage of sampling by laser melting is that molecular ion concentrations and stable water isotope compositions in ice cores can be measured at high depth resolution, which is advantageous for ice cores with low accumulation rates. This device takes highly discrete samples from ice cores, attaining depth resolution as small as ~3 mm with negligible cross contamination; the resolution can also be set at longer lengths suitable for validating longer-term profiles of various ionic and water isotopic constituents in ice cores. This technique allows the detailed reconstruction of past climatic changes at annual resolution and the investigation of transient ionic and isotopic signals within single annual layers in low-accumulation cores, potentially by annual layer counting.</p>