Abstract
A novel N4-planar Cu(II) macrocyclic fragment, namely, [CuL](ClO4)2 (I) (L = 4-methyl-1,3,6,8,11,14-hexaazatricyclo[12.2.1.18,11)octadecane has been prepared from a simple template condensation reaction and structurally characterized for the first time. The complex of I crystallizes in the monoclinic system of space group P21/c with unit cell parameters: a = 17.124(10), b = 9.255(5), c = 14.053(8) A and β = 111.262(7)°.
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