Abstract
A novel zinc(II) coordination polymer {[Zn(FcCOO) 2(bbbm)]·2H 2O} n (Fc=( η 5–C 5H 5)Fe( η 5–C 5H 4); bbbm=1,1′-(1,4-butanediyl)bis-1 H-benzimidazole) was obtained by the reaction of Zn(OAc) 2·2H 2O with bbbm and FcCOONa in methanol solution. The molecule reveals an infinite one-dimensional (1D) helical chain [Zn(bbbm)] n with the ferrocenecarboxylate anion as monodentate coordinating to the Zn ion. Its thermal and electrochemical properties were also investigated.
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