Abstract
Hydrothermal reaction of MnCl2·4H2O with H3PTC (PTC = pyridine-2,4,6-tricarboxylate) yields a novel three-dimensional manganese(II) coordination polymer, [Mn2(OH)(H2O)(PTC)] (1), constructed by Mn4 clusters and PTC linkers. Compound 1 displays five-connected BN topology, and there exists weak antiferromagnetic exchange interactions between the manganese(II) ions with g = 2.02, Jwb/k = −0.96 K, and Jbb/k = −1.07 K.
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