A novel electroless plating of Ni–P–TiO 2 nano-composite coatings

Abstract

A new processing concept has been developed to produce nano-structured metal-matrix composite coatings. This method combines sol-gel and electroless plating techniques to prepare highly dispersive oxide nano-particle reinforced composite coatings. Transparent TiO 2 sol was added into the standard electroless plated Ni–P solution at a controlled rate to produce Ni–P–TiO 2 nano-composite coatings on Mg alloys. The coating was found to have a crystalline structure. The nano-sized TiO 2 particles (∼ 15 nm) were well dispersed into the Ni–P coating matrix during the co-deposition process. This technique can effectively avoid the agglomeration of nano-particles in the coating matrix. As a result, the microhardness of the composite coatings were significantly increased to ∼ 1025 HV 200 compared to ∼ 710 HV 200 of the conventional composite coatings produced with solid particle mixing methods. Correspondingly, the wear resistance of the new composite coatings was also greatly improved.