Abstract
A novel Cu(II) coordination polymer of general empirical formula {[Cu(μ-HC2O4)2(H2O)2][Cu(HC2O4)2]∙6H2O}n (1) has been synthesized and characterized by single-crystal X-ray diffraction technique. The complex (1) crystallizes in the triclinic form with P-1 space group. It is quite surprising that single crystal X-ray analysis of 1 illustrates the presence of hydrogen oxalate ligand in the coordination environment of Cu(II) ion. Because oxalate is not present in the starting reaction mixture, it may be derived from the reduction of squarate ligand. In 1, Cu(II) ions exhibit two different coordination environments, forming a distorted octahedral geometry. The Cu1 is coordinated with six oxygen atoms from two bidentate HC2O4− and two aqua ligands, while Cu2 is coordinated with six oxygen atoms from four HC2O4− ligands. The HC2O4− ligand acts in two different coordination modes, as a bidentate and an unprecedented tridentate bridging coordination mode.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of Inorganic and Organometallic Polymers and Materials
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.