A novel copper-catalyzed, one-pot synthesis of symmetric organic disulfides from alkyl and aryl halides: potassium 5-methyl-1,3,4-oxadiazole-2-thiolate as a novel sulfur transfer reagent

Abstract

A new method is reported for the synthesis of symmetric diaryl and dialkyl disulfides from aryl and alkyl halides in the presence of copper using potassium 5-methyl-1,3,4-oxadiazole-2-thiolate as the base, ligand, and sulfur-transfer reagent.