Abstract

An exact solution of the van der Waals-Maxwell problem proposed by Gibbs in the parametric form is considered as a possible model for the reliable and consistent description of the coexistence curves in real fluids: Ar, C 2H 4, CO 2, H 2O from triple and up to the critical points. A simple rescaling procedure of the Gibbs parameter maps the van der Waals-Maxwell results into the phase diagram of real fluid.

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