Abstract
The hydrothermal reaction of Zn(NO 3) 2 · 6H 2O, bpp and NH 4VO 3 in water at 140 °C for 80 h yields an unprecedented chiral three-dimensional vanadium oxide complex, [Zn(bpp)V 2O 6] ( 1). The structure of 1 consists of wave-like two-dimensional networks, linked through {ZnO 2N 2} building blocks and bpp ligands into a three-dimensional covalently linked assembly. Furthermore, the title compound consists of infinite helical chains and all helical chains are left-handed.
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