A Novel Calcium Oxalate/Sepiolite Composite for Highly Selective Adsorption of Pb(II) from Aqueous Solutions

Abstract

Synthesizing functional nanomaterials from naturally abundant clay has always been of vital importance for resource utilization, however, the lack of new methods to effectively utilize low-grade clay presents a significant challenge. Herein, a calcium oxalate/sepiolite nanocomposite (SMN-x) was prepared by using the water bath heating method to convert the associated calcium carbonate in low-grade sepiolite into calcium oxalate. The developed composite was subsequently used to remove Pb(II) from the aqueous solutions. The SMN-3 adsorbent prepared by heating in a water bath at 90 °C for 3 h (with a high specific surface area of 234.14 m2·g−1) revealed the maximum Pb(II) adsorption capacity of 504.07 mg·g−1 at pH 5, which was about five times higher than that of sepiolite (105.57 mg·g−1). Further, the SMN-3 adsorbent possessed a much higher selectivity for Pb(II) as compared to the other metal ions. Moreover, the residue was noted to be stable and safe. The adsorption kinetics and isotherms conformed to the quasi-second-order kinetic and Langmuir models. During the adsorption process, ion exchange was noted to the main mechanism, however, it was also accompanied by electrostatic attraction. This study provides a novel strategy for the sustainable development of simple and efficient adsorbents by utilizing low-grade clay minerals.