Abstract

We report a successful synthesis of high quality non-polar m-plane (100) ZnO thin films via a novel and facile two step solution growth method. The reproducible growth of polarity free films is achieved by manipulating the seed/substrate characteristics, solution chemistry and growth conditions. Based on time resolved growth reaction FESEM analysis, three step growth phenomena viz. dissolution, recrystallization & primary growth and in situ nucleation/crystallization & secondary growth is proposed and explained.

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