A Novel and Universal Route to SiO2-Supported Organic/Inorganic Hybrid Noble Metal Nanomaterials via Surface RAFT Polymerization

Abstract

Polymer-encapsulated gold or silver nanoparticles were synthesized and sterically stabilized by a shell layer of poly(4-vinylpyridine) (P4VP) grafted on SiO(2) nanoparticles that acts as a scaffold for the synthesis of hybrid noble metal nanomaterials. The grafting P4VP shell was synthesized via surface reversible addition-fragmentation chain transfer (RAFT) polymerization of 4-vinylpyridine (4VP) using SiO(2)-supported benzyl 9H-carbazole-9-carbodithioate (SiO(2)-BCBD) as the RAFT agent. The covalently tethered P4VP shell can coordinate with various transition metal ions such as Au(3+) or Ag(+) and therefore stabilize the corresponding Au or Ag nanoparticles reduced in situ by sodium borohydride (NaBH(4)) or trisodium citrate. The SiO(2)-supported RAFT agent and the Au or Ag nanoparticles embedded in the P4VP shell layer were characterized by UV-vis spectrophotometer, X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and surface-enhanced Raman spectroscopy (SERS).