A novel and green fabrication of 3C-SiC nanowires from coked rice husk-silicon mixture and their photoluminescence property

Abstract

This work provides a novel and green approach to synthesize 3C-SiC nanowires (NWs) by carbothermic reduction of coked rice husk and silicon powders without catalyst or extra protective atmosphere. Results show that the as-synthesized 3C-SiC NWs are well-crystallized and grow along the [1 1 1] direction, the diameters of them are in the range of 50–120 nm, and their lengths are up to dozens of micrometers. They own a face-centered cubic structure and are wrapped by a thin amorphous SiO2 layer (∼6 nm). Meanwhile, a few stacking faults perpendicular to the growth direction exist in their crystals. These 3C-SiC NWs exhibit three ultraviolet light emission peaks at wavelengths of 435 nm, 467 nm and 572 nm, respectively, showing they possess a wide range of emission wavelengths. This study is of great significance which extends the research of 3C-SiC NWs and will bring great benefits to their practical applications in optoelectronic devices.