A novel AgNFs/MOF/CFC substrate-based flexible SERS sensor for high-sensitive detection of dye molecules

Abstract

Metal–organic framework (MOF) materials have been increasingly used owing to their high porosity, chemical stability, and semiconducting properties. With the help of MOF materials, MOF-based SERS substrates can exhibit high sensitivity. Herein, we proposed a flower-like Ag nanoparticles (AgNFs)/metal–organic framework (MOF)/ carbon fiber cloth (CFC) substrate-based surface-enhanced Raman scattering (SERS) sensor for the high-sensitive detection of dye molecules. MOF is used as a signal amplifier to accelerate the approach of dye molecules near AgNFs on the MOF surface and anchor AgNFs on the substrate surface. The detection occurred on the AgNFs/MOF/CFC SERS substrate, providing an enhancement factor (EF) of 5.53 × 107. Benefitting from the signal amplification function of AgNFs/MOF/CFC and the superiority of SERS, this sensor represented high sensitivity performance and a wide detection range. Importantly, the combination of Co elements with silver in the AgNFs/MOF/CFC composite substrate enhances the resistance of Ag to oxidation by atmospheric moisture resulting in excellent stability (the substrate maintained good SERS activity after 45 days of exposure to air) of the SERS substrate. The basic performance of the substrate was evaluated using rhodamine 6 G (R6G). (Detection limit reached 10−12 M) The detection limit of TC was 0.1 ppm. This method provides a potential and cost-effective strategy to develop advanced SERS sensing devices to effectively monitor pollutants in environmental waters.