Abstract
A novel (4,4,7)-connected 3D self-penetrating network with unprecedented 7-connectivity, has been constructed using 1,4-bis(2-methylbenzimidazol-1-ylmethyl) benzene and 3,3′,4,4′-Benzophenonetetracarboxylic acid as co-ligands. It represents an unusual self-penetrating pattern with the entanglements of nonequivalent 4- and 6-membered shortest rings.
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