Abstract
AbstractA cyclic‐tetranuclear [Ni4(H–1L)2(μ‐PhCOO)2(H2O)4](ClO4)4·2H2O (1) complex has been prepared by reaction of nickel (II) perchlorate with L (L = 3,5‐bis((bis(2‐hydroxylethyl)amino)methyl)‐4H‐1,2,4,‐triazol‐4‐amine) and benzoate sodium. The X‐ray structure shows that complex 1 consists of a cyclic tetranuclear nickel(II) cation and four uncoordinated ClO4– anions and two crystalline water molecules, in which four nickel atoms have distorted octahedral coordination. Magnetic studies indicate the existence of antiferromagnetic coupling between the nickel(II) ions. The interaction of the complex with calf thymus DNA (CT‐DNA) has been investigated by UV absorption and fluorescent spectroscopy, furthermore, DNA cleavage experiments show that the complex cleavages DNA through an oxidative mechanism.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.