Abstract
For aromatic polar and apolar solvents, the solvent dipolarities (-r*) from linear solvation free energy relationships (LSFE) can be correlated to their respective molecular dipole moments. The added secondary polarizability effects observed for these solvents usually have been rationalized in terms of the Onsager function in index of refraction. However, the interpretation of such secondary effects can be clarified by using a semiquantitative molecular orbital treatment of molecular polarizability-hyperpolarizabilities for the simple alkylbenzenes and halobenzenes.
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