Abstract

In the zinc hydrometallurgical purification process, the concentration ratio of zinc ion to trace nickel ion is as high as 105, so that the nickel spectral signal is completely covered by high concentration zinc signal, resulting in low sensitivity and nonlinear characteristics of nickel spectral signal. Aiming at the problem that it is difficult to detect nickel in zinc sulfate solution, this paper proposes a nonlinear integrated modeling method of extended Kalman filter based on Adaboost algorithm. First, a non-linear nickel model is established based on nickel standard solution. Second, an extended Kalman filter wavelength optimization method based on correlation coefficient is proposed to select wavelength variables with high signal sensitivity, large amount of information and strong nonlinear correlation. Finally, a nonlinear integrated modeling method based on Adaboost algorithm is proposed, which uses extended Kalman filter as a basic submodel, and realizes the stable detection of trace nickel through the weighted combination of multiple basic models. The results show that the average relative error of this method for detecting nickel is 4.56%, which achieves accurate detection of trace nickel in zinc sulfate solution.

Highlights

  • Zinc (Zn) is the third largest non-ferrous metal after aluminum and copper (Yadav and Banerjee, 2018)

  • In order to solve the problem that it is difficult to detect the concentration of nickel ion in zinc sulfate solution, this paper proposes a nonlinear integrated modeling method of extended Kalman filter based on Adaboost algorithm

  • Aiming at the nonlinearity of nickel in high-concentration zinc solution, based on the Kalman filter spectrophotometry, this paper proposes an extended Kalman filter spectrophotometric method based on ultraviolet-visible spectroscopy to detect nickel ion in high concentration zinc solution

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Summary

INTRODUCTION

Zinc (Zn) is the third largest non-ferrous metal after aluminum and copper (Yadav and Banerjee, 2018). In order to solve the problem that it is difficult to detect the concentration of nickel ion in zinc sulfate solution, this paper proposes a nonlinear integrated modeling method of extended Kalman filter based on Adaboost algorithm. The results show that the average relative error of this method for detecting nickel ion is 4.56%, which achieves accurate detection of trace nickel ion in high concentration zinc solution

Extended Kalman Filter
Integrated Modeling Based on Adaboost
Reagents
Apparatus
Procedures
Spectral Characteristics
Univariate Calibration
Extended Kalman Filter Spectrophotometry
Integrated Modeling Based on Adaboost Algorithm
Evaluation index
CONCLUSIONS
DATA AVAILABILITY STATEMENT
Full Text
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