A nonanuclear triangular macrocycle and a linear heptanuclear heterometallic complex based on a 2-substituted imidazole-4,5-dicarboxylate ligand.

Abstract

A Cp*Rh-based nonanuclear triangular macrocycle complex [(Cp*Rh)9L3(NO3)4.5(MeOH)](OTf)4.5 (1), a Cp*Ir-based trinuclear complex [(Cp*Ir)3L(MeCN)4](OTf)3 (2) and a linear heptanuclear heterometallic complex [(Cp*Ir)6ZnL2(MeCN)8(MeOH)2](OTf)8 (3) (Cp* = η(5)-pentamethylcyclopentadienyl) have been synthesized from a 2-(4-(pyridin-4-yl)phenyl)-1H-imidazole-4,5-dicarboxylic acid proligand. These complexes were further characterized by X-ray crystallography, (1)H NMR, DOSY NMR, IR spectroscopy, and elemental analyses.