Abstract
Abstract A two-dimensional Ni(II) coordination polymer (NiCP) of the formula {[NiL(terephthalate)(H2O)2]·2H2O} n (L = bis(1-(pyridin-4-ylmethyl)-benzimidazol-2-ylmethyl)ether), has been obtained from a solvothermal reaction, and characterized by single-crystal X-ray diffraction, elemental analysis, and IR and UV/Vis spectra. The coordinated terephthalate anions and the L ligands connect the Ni(II) ions in two directions, resulting in the construction of a corrugated layered structure. The electrochemical properties of a NiCP-CPE composite electrode supported by this coordination polymer were studied. For the electrocatalytic hydrogen evolution reaction, the required overpotential of this electrode (NiCP-CPE) is −521 mV when the current density reaches 10 mA cm−2. Compared with the solid carbon paste electrode (sCPE, −976 mV), the smaller overpotential proves effective electrocatalysis of the coordination polymer of the hydrogen evolution reaction. The doped electrode also exhibits high-efficiency in the electrochemical sensing of l-ascorbic acid in water, showing a detection limit of 0.28 μM in a linear range of 0.4–4000 μM.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.