Abstract
Data previously reported by Cheng and Eisenberg for catalysis of the water gas shift (WGS) reaction by platinum and tin chlorides have been reviewed. A new catalytic cycle for the WGS catalysis that is consistent with more recent studies and the experimental data for the Pt-Sn system is presented. It appears to be likely that the platinum intermediates have the trichlorotin ligand, but the exact nature of the catalytic intermediates is still unknown. 16 refs., 2 figs.
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