Abstract

A novel two-dimensional water layer which is trapped in a one-dimensional neodymium-organic arrays, [Nd 2(BC) 2(OX)(H 2O) 6] n · 10 nH 2O (BC 2− = 1,3-benzenedicarboxylate anion and OX 2 - = C 2 O 4 2 - ), is reported. There are puckered 6-, 12- and 16-membered rings existing in the water layer. The cyclic 6- and 12-membered rings in turn fuse together to generate the water tape, namely T6(3)12(3)6(2). The water layer is formed via the assembly of the T6(3)12(3)6(2) water tapes.

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