Abstract
A new synthetic approach, involving an S RN1 reaction of the anion of 1-methyl-4-phenylsulfonyl-methyl-5-nitro-1 H-imidazole with 2,2-dinitropropane and a radical anion or a concerted radical reductive elimination of sulfonyl and nitro groups affords an original 5-nitroimidazole bearing a trisubstituted ethylenic double bond at 4-position.
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