Abstract

Abstract The following compounds Tll3.L2 (whereL=triphenylphosphine-oxide, hexamethylphosphorotriamide, pyridine N-oxide, 2-,3- or 4-methylpyridine N-oxide, 2-mercaptopyridine N-oxide and dimethylsulphoxide), have been prepared and characterized by elemental analysis. The solids are monomers and non-electrolytes in acetonitrile solution. Possible molecular structures are given on the basis of 1H NMR and IR spectra, with particular attention on the νTl-1 and νTl-0 stretching modes.

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