Abstract
The highly diastereoselective osmylation of a C C bond in proximity to a complex fragment is the key step in the formation of 2 from the butadiene(tricarbonyl)iron complex 1. The diols 2 can be transformed readily into 3, key intermediates in the synthesis of 5,6-DiHETE and lipoxin A4. R SiPh2tBu; R′ Me; E CO2Me.
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Schedule a callMore From: Angewandte Chemie International Edition in English
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