A NEW STAR FORMATION RATE CALIBRATION FROM POLYCYCLIC AROMATIC HYDROCARBON EMISSION FEATURES AND APPLICATION TO HIGH-REDSHIFT GALAXIES

We present AKARI 2.5–5 μm spectra of 145 local luminous infrared galaxies (LIRG; LIR ≥ 1011 L⊙) in the Great Observatories All-sky LIRG Survey (GOALS). In all of the spectra, we measure the line fluxes and equivalent widths (EQWs) of the polycyclic aromatic hydrocarbon (PAH) at 3.3 μm and the hydrogen recombination line Brα at 4.05 μm, with apertures matched to the slit sizes of the Spitzer low-resolution spectrograph and with an aperture covering ∼95% of the total flux in the AKARI two-dimensional (2D) spectra. The star formation rates (SFRs) derived from the Brα emission measured in the latter aperture agree well with SFRs estimated from LIR, when the dust extinction correction is adopted based on the 9.7 μm silicate absorption feature. Together with the Spitzer Infrared Spectrograph (IRS) 5.2–38 μm spectra, we are able to compare the emission of the PAH features detected at 3.3 μm and 6.2 μm. These are the two most commonly used near/mid-infrared indicators of starburst or active galactic nucleus (AGN) dominated galaxies. We find that the 3.3 μm and 6.2 μm PAH EQWs do not follow a linear correlation and at least a third of the galaxies classified as AGN-dominated sources using the 3.3 μm feature are classified as starbursts based on the 6.2 μm feature. These galaxies have a bluer continuum slope than galaxies that are indicated to be starburst-dominated by both PAH features. The bluer continuum emission suggests that their continuum is dominated by stellar emission rather than hot dust. We also find that the median Spitzer/IRS spectra of these sources are remarkably similar to the pure starburst-dominated sources indicated by high PAH EQWs in both 3.3 μm and 6.2 μm. Based on these results, we propose a revised starburst/AGN diagnostic diagram using 2–5 μm data: the 3.3 μm PAH EQW and the continuum color, Fν(4.3 μm)/Fν(2.8 μm). We use the AKARI and Spitzer spectra to examine the performance of our new starburst/AGN diagnostics and to estimate 3.3 μm PAH fluxes using the James Webb Space Telescope (JWST) photometric bands in the redshift range 0 < z < 5. Of the known PAH features and mid-infrared high ionization emission lines used as starburst/AGN indicators, only the 3.3 μm PAH feature is observable with JWST at z > 3.5, because the rest of the features at longer wavelengths fall outside the JWST wavelength coverage.

Luminous infrared (IR) galaxies are key sites of obscured stellar mass assembly at z > 0.5. Their star formation rates (SFRs) are often estimated using the luminosities of the 6.2 and 11.2 μ m polycyclic aromatic hydrocarbon (PAH) features or those of the [Ne ii ] and [Ne iii ] fine-structure lines, as they are minimally affected by obscuration. It is uncertain whether the calibration of these features as SFR tracers depends on the starburst bolometric luminosity or the level of active galactic nucleus (AGN) activity. We here investigate the relationship between the luminosities of PAH and neon lines with SFR for highly luminous objects using radiative transfer modeling and archival observations of 42 local ultraluminous (≥10 12 L ⊙ ) IR galaxies (ULIRGs). We find that PAH and [Ne ii ] features arise mainly in star-forming regions, with small contributions from the AGN or host, but that the [Ne iii ] line has a mixed contribution from both star formation and AGN activity. We present relations between L PAH and L [Ne II ] , and both starburst luminosity and SFR. We find relations for lower-luminosity ( L IR ≃ 10 10 –10 12 L ⊙ ) systems underestimate the SFRs in local ULIRGs by up to ∼1 dex. The 6.2 and 11.2 μ m PAH features, and the [Ne ii ] line, are thus good tracers of SFR in ULIRGs. We do not find that a more luminous AGN affects the relationship between SFR and PAH or neon luminosity but that it can make PAH emission harder to discern. Our results and derived relations are relevant to studies of star-forming and composite galaxies at z < 3 with the James Webb Space Telescope.

Local luminous infrared galaxies: Spatially resolved mid-infrared observations with Spitzer/IRS

NGC 2316 is a young star cluster embedded in a dense cloud containing a central H II region powered by a B3 star. The ultraviolet (UV) radiation emitted by this young star affects the physical conditions and the chemical composition of the surrounding cloud. We present Spitzer Infrared Spectrograph (IRS) spectral maps of the polycyclic aromatic hydrocarbon (PAH) features and H2 lines in the 9-14 μm (SL1) and 15-20 μm (LL2) bands obtained using multiple slit positions. We show the distribution of 7.7 μm, 8.6 μm, 10-14 μm, 16-18 μm, and 19.0 μm PAH bands and the spatial variations among the bright narrow PAH features at 11.2, 12.0, 12.7, 16.4, 17.4, and 17.7 μm with distance from the ultraviolet (UV) source. We show that the Infrared Array Camera (IRAC) 8 μm emission is primarily due to the 7.7 and 8.6 μm PAH features. The IRAC 8 μm image of the entire cloud containing the cluster and the B3 star shows PAH emission on a large scale, not covered by IRS spectral data. We have also mapped the line intensities of three pure rotational H2 transitions: 0-0 S(1) Ortho 17.0 μm, 0-0 S(2) Para 12.3 μm, and 0-0 S(3) Ortho 9.7 μm. We detect a limb-brightened shell of H2 line emission at 15'' radius from the star. This H2 line emission in NGC 2316 is consistent with UV-pumped fluorescence in an H2 production zone. The correlation between the H2 and PAH emissions in the H2 shell suggest efficient formation of H2 by chemisorption on PAH surfaces. The intensities of all PAH features increase toward the UV source, but their relative contributions to the overall band emissions differ with the distance from the UV source. The detection of PAH emissions closest to the UV source implies the survival of PAHs in the intense, but softer UV radiation field of the B3 star. Using the radial intensities and a phenomenological model for PAH destruction as a function of distance from the UV source, we estimate the relative survival of the emitters (PAH components) in each spectrally resolved PAH emission feature. We identify four distinct PAH emission zones in NGC 2316 with a central UV source embedded in nearly spherical dense cloud with an average Av ~ 4.5 mag. Their emission characteristics and variations add new constraints to the PAH composition and excitation modes.

We use JWST/NIRCam and MIRI imaging acquired by the Feedback in Emerging extrAgalactic Star clusTers (or FEAST) program along with archival Hubble Space Telescope imaging to map ionized gas (Pa α , Br α , and H α ) and polycyclic aromatic hydrocarbon (PAH) emission (3.3 and 7.7 μ m) across a sample of four nearby galaxies (NGC 5194, 5236, 628, and 4449). These maps are utilized to calibrate the PAH features as star formation rate (SFR) indicators in 40 pc-size regions around massive emerging young star clusters. We find a tight, sublinear (power-law exponent α ∼ 0.8) relation between the PAH luminosities (3.3 and 7.7 μ m) and SFR (extinction-corrected Pa α ) in near-solar-metallicity environments. PAH destruction in more intense ionizing environments and/or variations in the age of our sources may drive the deviation from a linear relation. In the metal-poor environment of NGC 4449 (∼1/3 Z ⊙ ), we see substantial deficits in the PAH feature strengths at fixed SFR and significantly higher scatter in the PAH–SFR relations. We determine that the 3.3/7.7 μ m PAH luminosity ratio increases towards lower-metallicity environments. This is interpreted as a result of a shift in the size distribution towards smaller PAHs at lower metallicities, possibly due to inhibited grain growth. Focusing on the regions in NGC 4449, we observe a decreasing 3.3/7.7 μ m ratio towards higher SFR, which could indicate that small PAHs are preferentially destroyed relative to larger PAHs in significantly subsolar-metallicity conditions. We estimate that ∼two-thirds of the PAH emission in typical local star-forming galaxies is excited by older stars and unrelated to recent (<10 Myr) star formation.

We present results on low-resolution mid-infrared (MIR) spectra of 70 IR-luminous galaxies obtained with the infrared spectrograph (IRS) onboard Spitzer. We selected sources from the European Large Area Infrared Survey with S15 > 0.8 mJy and photometric or spectroscopic z > 1. About half of the samples are quasi-stellar objects (QSOs) in the optical, while the remaining sources are galaxies, comprising both obscured active galactic nuclei (AGN) and starbursts. Redshifts were obtained from optical spectroscopy, photometric redshifts and the IRS spectra. The later turn out to be reliable for obscured and/or star-forming sources, thus becoming an ideal complement to optical spectroscopy for redshift estimation. We estimate monochromatic luminosities at several rest-frame wavelengths, equivalent widths and luminosities for the polycyclic aromatic hydrocarbon (PAH) features, and strength of the silicate feature in individual spectra. We also estimate integrated 8–1000 μ mI R luminosities via spectral energy distribution fitting to MIR and far-IR (FIR) photometry from the Spitzer Wide-Area Infrared Extragalactic survey and the MIR spectrum. Based on these measurements, we classify the spectra using well-known IR diagnostics, as well as a new one that we propose, into three types of source: those dominated by an unobscured AGN, mostly corresponding to optical quasars (QSOs), those dominated by an obscured AGN and starburst-dominated sources. Starbursts concentrate at z ∼ 0.6–1.0 favoured by the shift of the 7.7-μm PAH band into the selection 15-μm band, while AGN spread over the 0.5 < z < 3.1 range. Star formation rates (SFR) are estimated for individual sources from the luminosity of the PAH features. An estimate of the average PAH luminosity in QSOs and obscured AGN is

Context. Mid- to far-infrared (IR) lines are suitable in the study of dust-obscured regions in galaxies because dust extinction strongly decreases with wavelength, and therefore IR spectroscopy allows us to explore the most hidden regions of galaxies, where heavily obscured star formation as well as accretion onto supermassive black holes at the nuclei of galaxies occur. This is mostly important for the so-called cosmic noon (i.e. at redshifts of 1 &lt; z &lt; 3), at which point most of the baryonic mass in galaxies has been assembled. Aims. Our goal is to provide reliable calibrations of the mid- to far-IR ionic fine-structure lines, the brightest H2 pure rotational lines, and the polycyclic aromatic hydrocarbon (PAH) features, which we used to analyse current and future observations in the mm-submm range from the ground, as well as mid-IR spectroscopy from the upcoming James Webb Space Telescope. Methods. We used three samples of galaxies observed in the local Universe: star-forming galaxies (SFGs, 196), active galactic nuclei (AGN; 90−150 for various observables), and low-metallicity dwarf galaxies (40). For each population, we derive different calibrations of the observed line luminosities versus the total IR luminosities. Results. Through the resulting calibrations, we derive spectroscopic measurements of the star formation rate (SFR) and of the black hole accretion rate (BHAR) in galaxies using mid- and far-IR fine-structure lines, H2 pure rotational lines and PAH features. In particular, we derive robust star formation tracers based on the following: the [CII]158 μm line; the sum of the two far-IR oxygen lines, the [OI]63 μm line, and the [OIII]88 μm line; a combination of the neon and sulfur mid-IR lines; the bright PAH features at 6.2 and 11.3 μm; as well as – for the first time – the H2 rotational lines at 9.7, 12.3, and 17 μm. We propose the [CII]158 μm line, the combination of the two neon lines ([NeII]12.8 μm and [NeIII]15.5 μm), and, for solar-like metallicity galaxies that may harbour an AGN, the PAH 11.3 μm feature as the best SFR tracers. On the other hand, a reliable measure of the BHAR can be obtained using the [OIV]25.9 μm and the [NeV]14.3 and 24.3 μm lines. For the most commonly observed fine-structure lines in the far-IR, we compare our calibration with the existing ALMA observations of high-redshift galaxies. We find an overall good agreement for the [CII]158 μm line for both AGN and SFGs, while the [OIII]88 μm line in high-z galaxies is in better agreement with the low-metallicity local galaxies (dwarf galaxy sample) than with the SFGs, suggesting that high-z galaxies might have strong radiation fields due to low metal abundances, as expected.

With advancement of infrared space telescopes during the past decade, infrared wavelength regime has been a focal point to study various properties of galaxies with respect to evolution of galaxies. Polycyclic Aromatic Hydrocarbons (PAHs) have emerged as one of the most important features since these features dominate the mid-infrared spectra of galaxies. These PAH features provide a great handle to calibrate star formation rates and diagnose ionized states of grains. However, the PAH 3.3 μ m feature has not been studied as much as other PAH features since it is weaker than others and resides outside of Spitzer capability, although it will be the only PAH feature accessible by JWST for high-z galaxies. AKARI mJy Unbiased Survey of Extragalactic Sources in 5MUSES (AMUSES) intends to take advantage of AKARI capability of spectroscopy in the 2 ~ 5 μ m to provide an unbiased library of 44 sample galaxies selected from a parent sample of 5MUSES, one of Spitzer legacy projects. For these 3.6 μ m flux limited sample galaxies whose redshifts range between 0 z μ m as a star formation rate (SFR) indicator while measuring ratios between PAH features. We present preliminary results of AMUSES.

We performed mid-infrared spectroscopic observations of 18 local dusty elliptical galaxies by using the Infrared Spectrograph (IRS) on board Spitzer. We have significantly detected polycyclic aromatic hydrocarbon (PAH) features from 14 out of the 18 galaxies, and thus found that the presence of PAHs is not rare but rather common in dusty elliptical galaxies. Most of these galaxies show an unusually weak 7.7 um emission feature relative to 11.3 um and 17 um emission features. A large fraction of the galaxies also exhibit H2 rotational line and ionic fine-structure line emissions, which have no significant correlation with the PAH emissions. The PAH features are well correlated with the continuum at 35 um, whereas they are not correlated with the continuum at 6 um. We conclude that the PAH emission of the elliptical galaxies is mostly of interstellar origin rather than of stellar origin, and that the unusual PAH interband strength ratios are likely to be due to a large fraction of neutral to ionized PAHs.

Machine learning feature importance calculations are used to determine the molecular substructures that are responsible for mid- and far-infrared (IR) emission features of neutral polycyclic aromatic hydrocarbons (PAHs). Using the extended-connectivity fingerprint as a descriptor of chemical structure, a random forest model is trained on the spectra of 14 124 PAHs to evaluate the importance of 10 632 molecular fragments for each band within the range of 2.761 to $1172.745\, \mu$m. The accuracy of the results is confirmed by comparing them with previously studied unidentified infrared emission (UIE) bands. The results are summarized in two tables available as Supplementary Data, which can be used as a reference for assessing possible UIE carriers. We demonstrate that the tables can be used to explore the relation between the PAH structure and the spectra by discussing about the IR features of nitrogen-containing PAHs and superhydrogenated PAHs.

In this paper, we present the Spitzer Infrared Spectrograph (IRS) low-resolution spectra of ultraluminous infrared galaxies with Seyfert spectral types from the 1-Jy sample. Among these sources, nine type 1 Seyfert galaxies and 17 type 2 Seyfert galaxies have Spitzer IRS low-resolution observations. For Seyfert 1 sources, we find that all sources have [Ne V] and/or [S IV] features, indicating an active galactic nucleus (AGN) nature, while many sources show polycyclic aromatic hydrocarbon (PAH) features, indicative of starburst activity. It is also found that most Seyfert 2 sources have mid-infrared spectra similar to that for Seyfert 1 sources, also indicating an AGN nature, and thus these could be classified as Seyfert 1-like sources. However, only a few sources have a normal Seyfert 2 nature and can be considered to be 'pure' Seyfert 2 sources. In addition, it is found that more prominent PAH features are found for Seyfert 2 sources, indicating strong star formation activity.

The mid-infrared spectrum contains rich diagnostics to probe the physical properties of galaxies, among which the pervasive emission features from polycyclic aromatic hydrocarbons (PAHs) offer promising means of estimating the star formation rate (SFR) relatively immune from dust extinction. This paper investigates the effectiveness of PAH emission as a SFR indicator on subkiloparsec scales by studying the Spitzer/IRS mapping-mode observations of the nearby grand-design spiral galaxy M51. We present a new approach of analyzing the spatial elements of the spectral data cube that simultaneously maximizes spatial resolution and spatial coverage, while yielding reliable measurements of the total, integrated 5–20 μm PAH emission. We devise a strategy of extracting robust PAH emission using spectra with only partial spectral coverage, complementing missing spectral regions with properly combined mid-infrared photometry. We find that in M51 the PAH emission correlates tightly with the extinction-corrected far-ultraviolet, near-ultraviolet, and Hα emission, from scales of ∼0.4 kpc close to the nucleus to 6 kpc out in the disk of the galaxy, indicating that PAH serves as an excellent tracer of SFR over a wide range of galactic environments. But regional differences exist. Close to the active nucleus of M51 the 6.2 μm feature is weaker, and the overall level of PAH emission is suppressed. The spiral arms and the central star-forming region of the galaxy emit stronger 7.7 and 8.6 μm PAH features than the inter-arm regions.

We present R ~ 600, 10-37 μm spectra of 53 ultraluminous infrared galaxies (ULIRGs), taken using the Infrared Spectrograph on board Spitzer. The spectra show fine-structure emission lines of neon, oxygen, sulfur, silicon, argon, chlorine, iron, and phosphorous; molecular hydrogen lines, and C_2H_2, HCN, and OH^- absorption features. We employ diagnostics based on the fine-structure lines, the polycyclic aromatic hydrocarbon (PAH) features and the 9.7 μm silicate absorption feature, to show that the infrared emission from most ULIRGs is powered mostly by star formation, with only ~20% of ULIRGs hosting an AGN with a greater IR luminosity than the starburst. The detection of [Ne V] λ14.32 in just under half the sample, however, implies that an AGN contributes significantly to the mid-IR flux in ~42% of ULIRGs. The starbursts and AGNs in ULIRGs appear more extincted, and for the starbursts more compact than those in lower luminosity systems. The excitations and electron densities in the narrow-line regions of ULIRGs appear comparable to those of starbursts with L ≾ 10^(11.5) L_⊙, although the NLR gas in ULIRGs may be more dense. We show that the [Ne II] λ12.81 + [Ne III] λ15.56 luminosity correlates with both infrared luminosity and the luminosity of the 6.2 and 11.2 μm PAH features, and derive a calibration between PAH luminosity and star formation rate. Finally, we show that ULIRGs with silicate absorption strengths Ssil of 0.8 ≾ S_(sil) ≾ 2.4 are likely to be powered mainly by star formation, but that ULIRGs with S_(sil) ≾ 0.8, and possibly those with S_(sil) ≳ 2.4, contain an IR-luminous AGN.&#13;\n

We report spectroscopic confirmation and high-resolution infrared imaging of a z=2.79 triply-imaged galaxy behind the Bullet Cluster. This source, a Spitzer-selected luminous infrared galaxy (LIRG), is confirmed via polycyclic aromatic hydrocarbon (PAH) features using the Spitzer Infrared Spectrograph (IRS) and resolved with HST WFC3 imaging. In this galaxy, which with a stellar mass of M*=4e9 Msun is one of the two least massive ones studied with IRS at z>2, we also detect H_2 S(4) and H_2 S(5) pure rotational lines (at 3.1 sigma and 2.1 sigma) - the first detection of these molecular hydrogen lines in a high-redshift galaxy. From the molecular hydrogen lines we infer an excitation temperature T=377+68-84 K. The detection of these lines indicates that the warm molecular gas mass is 6(+36-4)% of the stellar mass and implies the likely existence of a substantial reservoir of cold molecular gas in the galaxy. Future spectral observations at longer wavelengths with facilities like the Herschel Space Observatory, the Large Millimeter Telescope, and the Atacama Pathfinder EXperiment (APEX) thus hold the promise of precisely determining the total molecular gas mass. Given the redshift, and using refined astrometric positions from the high resolution imaging, we also update the magnification estimate and derived fundamental physical properties of this system. The previously published values for total infrared luminosity, star formation rate, and dust temperature are confirmed modulo the revised magnification; however we find that PAH emission is roughly a factor of five stronger than would be predicted by the relations between the total infrared and PAH luminosity reported for SMGs and starbursts in Pope et al. (2008).

Polycyclic aromatic hydrocarbon (PAH) dust emission has been proposed as an effective extinction-independent star formation rate (SFR) indicator in the mid-infrared, but this may depend on conditions in the interstellar medium. The coverage of the AKARI/Infrared Camera (IRC) allows us to study the effects of metallicity, starburst intensity, and active galactic nuclei on PAH emission in galaxies with f ν (L18W) ≲ 19 AB mag. Observations include follow-up, rest-frame optical spectra of 443 galaxies within the AKARI North Ecliptic Pole survey that have IRC detections from 7 to 24 μm. We use optical emission line diagnostics to infer SFR based on Hα and [O ii]λ λ3726, 3729 emission line luminosities. The PAH 6.2 μm and PAH 7.7 μm luminosities (L(PAH 6.2 μm) and L(PAH 7.7 μm), respectively) derived using multiwavelength model fits are consistent with those derived from slitless spectroscopy within 0.2 dex. L(PAH 6.2 μm) and L(PAH 7.7 μm) correlate linearly with the 24 μm dust-corrected Hα luminosity only for normal, star-forming “main-sequence” galaxies. Assuming multilinear correlations, we quantify the additional dependencies on metallicity and starburst intensity, which we use to correct our PAH SFR calibrations at 0 < z < 1.2 for the first time. We derive the cosmic star formation rate density (SFRD) per comoving volume from 0.15 ≲ z ≲ 1. The PAH SFRD is consistent with that of the far-infrared and reaches an order of magnitude higher than that of uncorrected UV observations at z ∼ 1. Starburst galaxies contribute ≳0.7 of the total SFRD at z ∼ 1 compared to main-sequence galaxies.