Abstract
A new, simple strategy has been formulated for the synthesis of deoxyamino sugars from a non-sugar starting material. Starting from the enantiomerically pure diol obtained from ethyl sorbate by Sharpless asymmetric dihydroxylation, the synthesis of two types of 2,3,4,6-tetradeoxy-4-amino sugars— d-tolyposamine and 4- epi- d-tolyposamine—, and formal synthesis of 2,4,6-trideoxy-4-amino sugar— d-vicenisamine—were performed.
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