A new scheme for ammonia and fertilizer generation by coal direct chemical looping hydrogen process: Concept design, parameter optimization, and performance analysis

Abstract

Ammonia is a very important chemical industry product. It has a wide range of applications in refrigeration, energy, and fertilizers , and 80% of ammonia is used as a nitrogen fertilizer. China mainly produces ammonia and urea from coal gasification , which leads to difficult CO 2 capture and high energy consumption. This study proposed a new process for the production of ammonia and urea by coal direct chemical looping hydrogen production process (CDCLTU). The coal direct chemical looping hydrogen production replaces the air separation unit and water gas conversion unit of the traditional coal-to-urea process (CTU), which effectively separates and captures CO 2 and significantly reduces the energy consumption. A model of the CDCLTU was established using Aspen Plus. Parameter optimization, technoeconomic, and environmental analysis were conducted through simulations. The results showed that CDCLTU could completely replace the air separation system that the CTU relies on. Compared with the traditional process, the utilization rate of C increased from 53.46% to 67.95% in the new process. The energy consumption of CO 2 separation and capture was reduced by 97.04%. The CDCLH had a 79.7% energy efficiency in the hydrogen production process and 99% capture rate of CO 2 . The total capital investment was dropped by 41%, unit urea production cost dropped by 12.1%, and the payback period dropped from 7.5 to 3.5 years. This paper provides a new direction for clean and efficient utilization of coal resources. • Proposed a novel coal-to-urea process by chemical looping technology. • Conducted main parameters optimization and performance analysis for the new process. • The new process reduced 97.04% energy consumption of CO 2 separation and capture. • Production cost of the new process is 12.1% lower than that of the conventional process. • The new process achieved 67.95% C utilization rate and 1.39 t/t lower CO 2 emission.