Abstract
A new sandwich polyoxometalate Na4Zn2[Zn2(H2O)10(ZnCl)6(B-α- BiW9O33)2] · 40.5H2O (1) has been obtained in aqueous solution and characterized by IR, UV, element analysis, TG and single-crystal X-ray analysis. Polyoxoanion 1 is composed of a Zn 6 12+ hexagon sandwiched by two [BiW9O33]9− units, which is firstly observed in tungstobismutate. The crystal data for compound 1: Triclinic, space group P–1, a = 15.426(3) A, b = 15.467(3) A, c = 15.526(3) A, α = 74.24(3)°, β = 64.37(3)°, γ = 60.73(3)°, V = 2905.3(1) A3, Z = 1.
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