Abstract
The rearrangement of a trichloro-pyrrolidin-2-one, prepared by the CuCl–TMEDA catalyzed atom transfer radical cyclization of N-alkyl- N-(3-chloro-2-propenyl)-2,2-dichloromyristamide, with n-propylamine or CH 3ONa/CH 3OH, is the key step of a new, short and inexpensive route to chaetomellic anhydride C and (±)- erythro-roccellic acid.
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