Abstract
For the investigation of complex thermal decomposition reactions, i.e. consecutive or reversible reactions, a new reactor has been developed, viz. a gradientless reactor operated like a batch reactor with a programmed linear temperature rise. As the result of the gas circulation in the reactor an accumulation is enforced. Only in this way can consecutive reactions be observed in which gaseous decomposition products participate. In connection with the well-known flush reactor it is possible to investigate the total reaction as well as the single reaction steps. The results from experiments with the new gradientless reactor and a flush reactor indicate characteristic differences in the case of the decomposition reactions of active coke loaded in flue gas cleaning experiments. A reaction scheme for the decomposition of sulfuric acid and ammonium sulfates is also derived.
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