A new reaction of nitrosyl complexes; one-electron reduction of trans-[MX(NO)L4]2+[M = Ru or Fe, X = Cl or Br, L = pyridine or o-phenylenebis(dimethylarsine)] with hydroxylamine

Kimitake Aoyagi,Hidetake Kakihana,Kunio Shimizu,Masao Mukaida

doi:10.1039/dt9850001733

A new reaction of nitrosyl complexes; one-electron reduction of trans-[MX(NO)L4]2+[M = Ru or Fe, X = Cl or Br, L = pyridine or o-phenylenebis(dimethylarsine)] with hydroxylamine

Kimitake Aoyagi, Hidetake Kakihana + Show 2 more

https://doi.org/10.1039/dt9850001733

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Journal: Dalton Trans.	Publication Date: Jan 1, 1985
Citations: 7

#Reaction Of Nitrosyl Complexes #Reaction Of Complexes + Show 3 more

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Abstract

The complexes trans-[MX(NO)L4]2+[M = Ru or Fe, X = Cl or Br, L = pyridine or o-phenylenebis(dimethylarsine)] react with hydroxylamine to afford the corresponding one-electron reduced species. The reaction appears to be the first to produce a (M–NO)2+ group.

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