Abstract

The use of potassium osmate, K 2[OsO 2(OH) 4], as a precursor for some cyclopentadienyl-osmium complexes is described. The X-ray structures of OsBr(PPh 3) 2Cp, OsCl(dppe)Cp and OsX(dppe)Cp ∗ (X = Cl, Br) are reported.

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