Abstract

A general and rigorous new formulation of the multicomponent extension to the Mayo Lewis copolymerization equation is presented based in matrix notation. In contrast to the original Walling and Briggs formulation, which was based on determinants and difficult to apply in practice, this new formulation is explicit, easy to implement, and introduces a natural scaling to the problem. The approach is illustrated with calculation of instantaneous composition and compositional drift with conversion for 4 and 6 monomers.

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