A new mixed ligand coordination polymer of Mn(II): structural aspect and cryomagnetic study

Abstract

A new 1-D polymeric chain complex [Mn(pydc)(1,10-phen)]n· nH2O (pydc = pyridine-2,3-dicarboxylate, 1,10-phen = 1,10-phenanthroline) has been synthesised and characterised by elemental analysis, FT-IR spectrum, thermal analysis and variable temperature magnetic susceptibility studies. Single crystal X-ray diffraction study reveals that the central Mn(II) ion is in a distorted octahedral coordination geometry, and is coordinated to pydc and 1,10-phen. The complex shows interesting hydrogen bond modes involving the dicarboxylates and lattice water molecules. The presence of weak antiferromagnetic coupling with J = −0.72 cm−1 for the complex has been concluded from the cryomagnetic susceptibility studies.