Abstract
A molybdenum (IV) phosphate containing lead, Pb 2Mo 2(PO 4)2P 2O 7, has been synthesized for the first time. It crystallizes in the space group C2/ c with a=14.098(1) Å, b=14.187(2) Å, c=6.5592(4) Å and β=102.08(1)°. Its original tunnel structure, built up of Mo 2O 11 bioctahedra, P 2O 7 and PO 4 phosphate groups can be described from the assemblage of [Mo 4P 4O 24] ∞ ribbons interconnected through monophosphate groups. The stereoactivity of the 6 s 2 lone pair of Pb 2+, which is surrounded by nine oxygen atoms, is discussed.
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