Abstract
A room-temperature reaction between [Re 6S 8(OH) 6] 4− and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re 6S 8(CH 3COO) 6] 4−. The complex was isolated as a potassium salt with the composition of K 4[Re 6S 8(CH 3COO) 6]·8H 2O ( 1) and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV–Vis, and luminescence spectroscopies.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
