Abstract
A mixed tetranuclear cluster of ruthenium and cobalt, namely undecacarbonyl-tri-μ-hydrido-(tricyclohexylphosphine)trirutheniumcobalt, [CoRu3H3(CO)11(C18H33P)], has been synthesized by reaction between Co2(CO)8 and the electron-deficient cluster [Ru3H2(CO)6(PCy3)3]. The compound was characterized, both spectroscopically and crystallographically. The molecular structure of [CoRu3(μ-H)3(μ-CO)(CO)10(PCy3)] shows a tetrahedral metal core. The tris(cyclohexyl)phosphine ligand is attached in an axial position to one of the Ru atoms of the basal face.
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