Abstract

Abstract Titanium(IV) chloride-catalyzed addition of diethyl trimethylsilyl phosphite to β-nitrostyrenes affords α-phosphoryl nitronates which, on treatment with low valent titanium in situ generated from titanium(IV) and zinc, are smoothly converted to 1-aryl-1-cyanomethanephosphonates in good yields.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.