Abstract
Abstract The present paper describes the synthesis, structural features and antimicrobial activity of some newly synthesized diorganosilicon(IV) complexes with benzothiazolines derived from ketones. The resulting complexes have been subjected to elemental analyses, conductance measurements, molecular weight determination and electronic, infra-red, 13C and 1H NMR spectral studies and their plausible structures have been discussed. Spectral data support a five-coordinate presumably trigonal bipyramidal geometry for 1:1 complexes, whereas 1:2 complexes are six-coordinated with an octahedral geometry. A few representative complexes along with their ligands have also been screened for their fungicidal as well as insecticidal activities and found to be quite active in this respect.
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