Abstract

In the title polymer chain, catena-poly[[[hexa-μ2-hydroxido-hexa-μ3-oxido-deca­oxido-chromium(III)hexa­molybdenum(IV)]-μ2-oxido-[hepta­aqua­neodymium(III)]- μ2-oxido] tetra­hydrate], [NdCrMo6O18(OH)6(H2O)7]·4H2O, the Nd atom has a tricapped trigonal-prismatic environment, being coordin­ated by two terminal O atoms from different [Cr(OH)6Mo6O18]3− units, and by seven water mol­ecules. In the crystal structure, hydrogen bonds result in the formation of a three-dimensional network and may be effective in the stabilization of the structure.

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