Abstract
Photolysis of 2,3:4,6-di-O-isopropylidene-2-keto-L-gulonic acid 1 and methyl-2,3-O-isopropylidene-β- d-ribofuranosiduronic acid 2 mediated by (diacetoxy)iodobenzene in the presence of protonated heteroaromatic bases provides a new stereoselective synthesis of C-nucleosides and C-nucleoside analogues, via radical pathways.
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