Abstract
(1S, 2R, 7R, 7aR)- 1,2,7-Trihydroxypyrrolizidine ( 1) is prepared by elaboration of an erythrose derivative ( 4) via an asymmetric allylation reaction; this approach promises to be widely applicable to syntheses of polyhydroxylated indolizidine and pyrrolizidine alkaloids.
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