Abstract

Wettability is a key factor controlling the flow of fluids, solutes, heat and electrical current in porous media, and therefore it is important in studies of various processes including CO2 storage, secondary and tertiary oil recovery, as well as the displacement of water and nonaqueous phase liquid (NAPL). Although Amott-Harvey and USBM are conventional industry-standard techniques for measuring average wettability, they have some limitations. In this paper, we show that, in a plot of the relative permeability of a fluid, the area below the curve is closely related to the wettability. By using the areas below the water and oil relative permeability curves, we derive a new wettability index (called modified Lak). To demonstrate the applicability of this new index and testing other indices, we performed primary imbibition relative permeability, and primary imbibition and secondary drainage capillary pressure measurements on twenty carbonate reservoir samples. In general, all indices predicted oil-wet character of the tested rocks. USBM was associated with the broadest range of variation, whereas the new index corresponded to the smallest range of variation. Amott-Harvey and Lak, however, fell between USBM and the new index, with fairly similar ranges of variation. In addition, we report the correlations between different indices, and the change of wettability indices vs. reservoir depth. Advantages and limitations of different wettability indices are also discussed. Since each wettability index has some limitations in revealing the true state of wettability, none of these indices can be considered as an absolute measurement. Therefore, different indices should be regarded as complementary to each other, and determination of wettability should not be limited to only one method.

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