Abstract

“Concentrated solar power” (CSP) and thermal energy storage (TES) are promising renewable energy technologies, which have gained increasing interest and practical application in recent years. CSP and TES systems typically utilize molten salts such as the so-called “solar salt”, a mixture of 60 wt.% NaNO3 and 40 wt.% KNO3, for heat transfer and storage. The overall efficiency of commercially operating CSP and TES systems is currently limited, because of solar salt thermal stability, which prevents process temperatures higher than 600 °C. Even at these temperatures, corrosion of the structural materials applied in salt guiding pipework, tubes and containers is a matter of concern in long-term operation, which necessitates careful material selection. This paper outlines the superior salt corrosion behavior of a novel low-cost, Al2O3-forming, ferritic, Laves phase-strengthened (i.e., structural) steel in NaNO3/KNO3 solar salt at 600 °C. Directions for the further development of the LB2230 trial steel towards improved structural properties are derived in comparison to its predecessor Crofer®22 H.

Highlights

  • In air at temperatures higher than 1000 ◦ C, austenitic Haynes 214 and ferritic LB2230 form protective Al2 O3 scales, while mixed chromia/alumina layers will form below this temperature [38,45]

  • The addition of aluminum forms a tightly adhering Al2 O3 layer, which protects against chromium vaporization

  • Information on corresponding temperature limits for the formation of protective α-Al2 O3 in solar salt is neither available for Haynes 214 nor LB2230

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Summary

Introduction

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. The demand for clean, renewable, efficient and affordable energy technologies rises due to the limited supply of fossil resources and the impact of CO2 emissions on global warming. In combination with thermal energy storage (TES), efficiency [1] and capacity make concentrating solar power (CSP) plants a very promising solution for the provision of uninterrupted base-load electricity supply. -called Carnot batteries or storage plants [2,3,4,5,6,7]

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