A new approach to generalizing riparian water and air quality function across regions.

Abstract

There is growing interest in generalizing the impact of hydrogeomorphology and weather variables on riparian functions. Here, we used RZ-TRADEOFF to estimate nitrogen, phosphorus, water table (WT) depth, and greenhouse gas (GHG: N2O, CO2, CH4) functions for 80 riparian zones typical of the North American Midwest, Northeast (including Southern Ontario, Canada), and Mid-Atlantic. Sensitivity to weather perturbations was calculated for temperature and precipitation-dependent functions (CO2, phosphate concentration, and water table), and multivariate statistical analysis on model outputs was conducted to determine trade-offs between riparian functions. Mean model estimates were 93.10cm for WT depth, 8.45mgNL-1 for field edge nitrate concentration, 51.57% for nitrate removal, 0.45mg PO43-L-1 for field edge phosphate concentration, 1.5% for subsurface phosphate removal, 91.24% for total overland phosphorus removal, 0.51mgNm-2day-1 for N2O flux, 5.5gCm-2day-1 for CO2 fluxes, and - 0.41mgCm-2day-1 and 621.51mgCm-2day-1 for CH4 fluxes in non-peat sites and peat sites, respectively. Sites in colder climates were most sensitive to weather perturbations for CO2, sites with deep water tables estimates had the highest sensitivity for WT, and sites in warm climates and/or with deep confining layers had the lowest sensitivity for phosphate concentration. Slope, confining layer depth, and temperature were the primary characteristics influencing similarities and trade-offs between sites. This research contributes to understanding how to optimize riparian restoration and protection in watersheds based on both water (nitrogen, phosphorus) and air quality (GHG) goals.