Abstract

A novel 3D anionic microporous metal-organic framework, Cu2(H4DCPPA) (ZJU-71, H4DCPPA=[1,1′:2′,1′′-terphenyl]-4,4′,4′′,5′-tetracarboxylic acid, ZJU=Zhejiang University), has been synthesized and structurally characterized. ZJU-71 possesses one-dimensional channels along a axis and a scu type topology. The negative electricity of the framework makes ZJU-71 an candidate for effective elimination of cationic contaminants.

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